Boilers
Boilers burn fuel to generate steam for space heating, hot
water, and generating electric power. The environmental impact of boilers
can arise from air emissions from fuel combustion, wastewater from cooling
and cleaning, and solid waste from ash disposal. This page describes
the potential impacts, the rules that have been developed to deal with the
impacts, and the associated compliance requirements.
In addition to verifying
compliance with the regulations, facilities
are advised to implement a comprehensive energy audit. Finding opportunities
to minimize
energy requirements will in turn minimize the load on boilers, leading
to lower fuel consumption and minimizing waste generation.
What
goes in; what comes out
Fuels
Boilers commonly use gas, oil, coal, solid waste, or a combination
of these depending on fuel availability, price and when the units were installed.
Pollutants
- Air Emissions from boilers include
- Smog producing compounds:
- nitrogen oxides
- volatile organic compounds
In the presence of sunlight, these materials combine
to produce ground-level ozone, which can:
- exacerbate asthma
- cause lung damage
- irritate eyes
- damage plant life
- Particulate matter: Fine particles can
lodge in the lungs and cause respiratory difficulties.
- Carbon monoxide: combines with hemoglobin
and prevents oxygen transport.
- Sulfur dioxide: a component of acid rain
- Air Toxins (Toxics): Air toxics are known to
cause or are suspected of causing adverse health effects in humans and
the environment
- Greenhouse Gases: Carbon dioxide, a product
of combustion sources, is a greenhouse gas that contributes to global warming.
Non-combustion wastes are generated from activities related
to operating boilers and are typically released to water. Non-combustion
wastes include:
- once-through cooling water
- cooling system blowdown
- boiler blowdown
- water-side boiler cleaning
- demineralizer regenerant
Bottom and fly ash and flue gas desulfurization (FGD)
wastes result from combustion but are not released through the stack. Ash
is typically a solid waste and FGD waste can either be a solid waste or a
slurry. Because ash can contain heavy metals and other hazardous components
it should be disposed of properly
Pollutant Releases by Fuel Type
Fuel |
Air Emissions |
Non-Combustion Waste |
Combustion Waste |
Coal |
- SO2
- NOx
- CO
- VOC
- PM
- metals
- arsenic
- beryllium
- cadmium
- chromium
- mercury
- lead
- selenium
- sulfur
|
-
chlorine
-
organic
chemicals
-
metals
-
pH
-
TSS
-
TDSS
-
ferrous
sulfate
-
sulfuric
acid
-
pyrite
|
- heavy metals
- ferrous sulfate
- sulfuric acid
- sulfate
- CaSO3
- CaO
|
Oil |
- SO2
- NOx
- CO
- VOC
- PM
- metals
- arsenic
- beryllium
- cadmium
- chromium
- sulfur
- organic HAPs
- HCI
|
- chlorine
- organic chemicals
- metals
- pH
- TSS
- TDSS
- ferrous
sulfate
- sulfuric acid
|
|
Gas |
|
- chlorine
- organic chemicals
- metals
- pH
- TSS
- TDSS
- metals
|
|
SO2 - Sulfur Dioxide
NOx -Nitrogen Oxides
CO - Carbon Monoxide
VOC - Volatile Organic Compounds |
PM - Particulate Matter
HAP - Hazardous Air Pollutant
TSS - Total Suspended Solids
TDSS - Total Dissolved + Susp. Solids |
Compliance Requirements
Please note: Your facility
may be covered by state and local regulations that may involve additional
requirements or more stringent standards than the federal standards summarized
here.
EPA has compiled a list
of state air pollution agency contacts as part of a recent effort to
develop National
Emissions Standards for Hazardous Air Pollutants (NESHAP) rules for boilers. This
list is not comprehensive or updated, but may help you locate further information
for your state.
In general, to minimize adverse environmental impacts and
ensure operator safety, boilers must be operated and maintained by trained
staff in accordance with the manufacturers' specifications. In
addition, there are a number of federal standards and regulations that apply
to boiler operations. The rest of this section contains a summary of
the applicable rules.
Clean Air Act (CAA)
New Source Performance Standards
Boilers at veterinary facilities, especially those with heat
input capacities equal to or greater than 2.9 megawatts or 10 million Btu/hr
may be subject to one of the New Source Performance Standards (NSPS) for steam
generating units:
- NSPS Subpart Dc applies to smaller boilers (between 10
and 100 million BTU/hr) constructed modified or reconstructed after June
8, 1989.
- NSPS Subpart Db applies to larger boilers (greater than
100 million BTU/hr) constructed modified or reconstructed after June 19,
1984.
Depending on the type of fuel combusted, the regulations
have emission standards for sulfur dioxide, nitrogen oxides and particulate
matter.
Owners and operators of boilers subject to Subparts Db and
Dc may be required to install:
- pollutant control devices, such as fabric filters
- monitoring equipment, such as opacity monitors or NOx
continuous emission control monitors
Boilers subject to these standards will also be required
to:
- submit notifications prior to construction and
operation
- conduct initial performance tests
- maintain records, e.g. fuel usage and monitoring system
operations
To check on the latest new source performance standards regulations see the NSPS boiler page.
Citation |
Applicability |
Pollutants Addressed |
40
CFR Part 60 subpart Db |
- Steam generating unit
- constructed, modified or reconstructed after 6/19/84
- heat input capacity > 100 million Btu per hour
|
|
40
CFR part 60 subpart Dc |
- Steam generating unit
- constructed, modified or reconstructed after 6/9/89
- heat input capacity between 10 million and 100 million Btu per hour
|
|
40 CFR Part 60 Subpart A |
Note that if an NSPS standard applies, facilities
must comply with the NSPS General Provisions in Subpart A |
|
National Emission Standards for Hazardous Air Pollutants
Boilers. Boilers at medical facilities that are major sources for Hazardous Air Pollutants under the Clean Air Act (potential to emit 10 tons/yr of a HAP or 25 tons/yr of a combination of HAPs) may be subject to the Industrial, Commercial and Institutional boilers and process heaters standard, if another NESHAP standard doesn't already apply. Facilities that are part of a larger entity, such as a university, prison or military base would be the most likely facilities to be major HAP sources under the CAA .
Citation |
Applicability |
Regulated Pollutants |
40 CFR
63
Subpart DDDDD |
- Industrial, commercial
and institutional boilers and process heaters with heat input capacity
greater than 10 million Btu/hour
- electric power
generators burning materials other than fossil fuels (e.g., wood
waste)
- Major HAP source,
not subject if other NESHAP applies
|
- PM
- arsenic
- cadmium
- chromium
- HF
- lead
- magnesium
- mercury
- nickel
|
40 CFR
Part 63 Subpart A |
Note
that if an
NESHAP standard applies, facilities must comply with the NESHAP General
Provisions in Subpart A |
|
More information, including an explanatory brochure, applicability
flowchart and rule language, is available from the boiler
NESHAP development page on the EPA website.
Boilers that burn alternative fuels other than fossil fuels,
including solid waste, may be subject to additional combustion regulations.
Boilers and Industrial Furnaces (BIF) that use
or burn fuel containing hazardous waste must comply with design and operating
standards. BIF regulations (40 CFR part 266, Subpart H) address unit design,
provide performance standards, require emissions monitoring, and in some
cases, restrict the type of waste that may be burned.
Asbestos
Any facility that contains asbestos, often used in insulation
for boilers and pipes, is subject to the Asbestos
National Emission Standard for Hazardous Air Pollutants (NESHAP). The Demolition
and Renovation standard stipulates EPA notification and proper handling and
disposal when asbestos containing material is disturbed.
Title
V of the Clean Air Act mandates that states compile all applicable standards,
such as those that apply to boilers, into a single permit for each major
source.
Find more information on asbestos on the Asbestos
page, and find information for your state on the Asbestos
State Regulation Locator.
NOx SIP Call
On September 24, 1998, EPA finalized a "Finding of Significant
Contribution and Rulemaking for Certain States in the Ozone Transport Assessment
Group Region for Purposes of Reducing Regional Transport of Ozone" (commonly
known as the "NOx SIP Call") requiring 22 States and the District
of Columbia to submit State implementation plans that address the regional
transport of ground-level ozone. The rule requires emission reduction measures
to be in place by May 1, 2003. These measures will include controls on ozone
precursors, such as NOx, emitted by fossil fuel-fired boilers and power generation
units.
Boilers with a rated capacity over 250 million BTUs that
are located in the eastern half of the US should be in contact with their state
permitting agencies to see how this may apply.
More information is available on an information
page on the NOx SIP Call provided by EPA.
Clean Water Act (CWA)
Water used to maintain boilers, which can contain contaminants
like those listed below, must be managed in accordance with the facility's
pretreatment program if, as in most cases, the facility discharges to a Publicly
Owned Treatment Works. Likewise, if the facility is a direct discharger the
effluent standards for contaminants would be addressed in the CWA
National Pollutant Discharge Elimination System (NPDES) permit.
Waste Streams and Effluent Limitations
Waste Stream |
BAT Effluent Limitation Guidelines |
All discharges |
pH, poly-chlorinated biphenyls (PCBs) |
Bottom ash transport waters and low volume waste sources |
TSS, oil and grease |
Chemical boiler metal cleaning wastes |
TSS, oil and grease, iron, copper |
Non-chemical metal cleaning wastes |
Reserved (low volume wastewater limits apply) |
Fly ash transport water (including economizer ash) |
No discharge allowed (based on availability of dry disposal methods
and the potential for reuse of fly ash transport water) |
Once-through cooling water |
Total residual chlorine (TRC) of free available chlorine (FAC), depending
on facility's generating capacity |
Cooling water blowdown |
FAC, chromium, zinc, other 126 priority pollutants where they are found
in chemicals used for cooling tower maintenance |
Coal pile runoff |
TSS |
Waste Ash
Ash from boilers fueled strictly by oil and coal may be
subject to disposal requirements at the state level. It is not regulated as
hazardous waste at the federal level.
Note that oil combustion wastes managed in unlined settling
basins may pose potential ground-water pathway risks for three pollutants:
arsenic, nickel, and vanadium. EPA determined, however, that oil combustion
wastes do not warrant regulation as hazardous wastes under RCRA Subtitle C
(65 Federal Register 32213, May 22, 2000).
More resources
The EPA Air Toxics website provides a convenient index
page for all combustion-related rules.
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